I only have experience with the ZRC cold galvanizing compound. When I first
read your post I thought what a good time to review my old chemistry and
valence bonding etc. After looking up the valence shells for AL, FE, and ZN I
thought, screw that I'll just offer my opinion.
I painted my Rohn 45 20 years ago with a couple of quarts of ZRC cold
galvanizing. The cans are heavy and the contents look like liquid zinc. ZRC
says it is about 95% zinc flakes. Looking up their FAQ they claim that it does
perform the galvanic bond as the flakes bond together and the carrier dries.
In my case I painted it over an already painted red/orange and white
transmitter tower. I power washed the tower first and knocked off as much of
the paint as I could, cleaned up any small rust spots and then painted it with
the ZRC. The ZRC is tough stuff. It hasn't flaked in 20 years/2 QTHs and if
you pull a rope over a wrung it will polish the spot to a shiny silver bare
metallic sheen. I would have to agree that the stuff bonded well to the tower.
I suppose I could make some ohmic measurements from inside surface to outside
surface the next time I have it down and see if it is electrically bonded as
well but don't expect that measurement this week.
Earl
N8SS
------------------------------
Message: 8
Date: Sat, 29 Nov 2014 04:54:48 +0000
From: Donald Chester <k4kyv@hotmail.com>
To: "towertalk@contesting.com" <towertalk@contesting.com>
Subject: [TowerTalk] Aluminium Paint versus Cold Galv
Message-ID: <BAY179-W22650B81B5ECE26B6DC9CBF47F0@phx.gbl>
Content-Type: text/plain; charset="iso-8859-1"
Reviewing the archives, I see many posts over the years on the subject Cold
Galvanising paint. Some say it works wonders while others have reported it
being no better than ordinary paint.? Here is my experience.
I once used a spray can of Cold Galv on another outdoor steel structure, and
recall rust spots creeping through within just a few months. I have used
aluminium paint on unprotected steel, and on galvanised steel showing signs of
rust, and it always seems to last a long time before more rust appears. The
steel casting on the salvaged broadcast station base insulator I use with my
tower was not galvanised at the factory. After erecting the tower I painted the
ungalvanised casting with aluminium paint, and in the 33 years that I have had
the tower up, I have re-painted it only once. Aluminium paint seems to be
almost as good as hot-dip galvanising for warding off rust, and I believe it is
a more effective product than Cold Galv for protecting steel.
Here is a brochure from ALCOA touting the advantages of aluminium paint. See
https://ia601502.us.archive.org/33/items/AluminumPaintATreatiseOnThePhysicalPropertiesOfAluminumPaintAndIts/AluminumCoOfAmericaCca39891.pdf
According to the brochure, "Many power companies are finding aluminium paint
more satisfactory than galvavizing for protecting the steel towers used in
supporting power lines... In painting towers, bridges and structures in
general, the painter appreciates the difference in weight... Since the
corrosion of iron and steel is caused by moisture and oxygen, it is obvious
that a highly impermeable paint film is desirable for their protection"
ALCOA goes on to say, "The metallic aluminium flakes, called aluminium bronze
powder, which are its pigment portion, have many unique and useful properties
which no other paint pigment has. The simple mixing of this aluminium bronze
powder with a suitable oil or varnish vehicle at once provides an aluminium
paint which renders unusually satisfactory service in many and varied
applications... Aluminium bronze powder for paints is made by stamping
aluminium into very small and thin flakes... The shape of the particles of
aluminium bronze powder is of particular interest. The ordinary pigment
materials like zinc oxide, red lead, white lead, etc., are composed of
particles distinctly granular in form even though they be exceedingly small.
Aluminium bronze powder is, however, essentially flake-like in character...
little particles of aluminium swirl about in the liquid and many of them come
to the surface of the liquid and remain there... Very quickly an almost
continuous film o
f metallic aluminium is formed at the surface of the varnish by the little
flakes... which arrange themselves, in layer upon layer, much like fish
scales... descriptively called LEAFING..."
Of course, one must keep in mind that ALCOA is promoting their product, but
still this is a credible explanation. Cold Galv uses tiny particles of zinc
suspended in the vehicle/bonding agent of the paint to coat the steel, on the
theory that the zinc particles will protect the steel in the same manner as the
solid layer of zinc in real galvanising. But with hot-dip galvanising, the zinc
coating is directly bonded to the steel like solder, making electrical contact
with the steel substrate. By galvanic action (hence the term "galvanising"),
the zinc sacrifices itself in the presence of corrosive substances like
sulphuric acid in polluted air, thus protecting the steel from rust. With zinc
paint, the particles are suspended in the varnish-like vehicle of the paint,
which continues to serve as a bonding agent after the paint dries. Since
varnish is an electrical insulator, not a conductor, each zinc particle is
effectively isolated from the steel it is supposed to protect, so ho
w could any galvanic action occur?
Don k4kyv
------------------------------
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